Synthesis of Dinaphtho-dioxaphosphepin-4-oxides, Epoxides and Bisphosphonates

A few new seven-membered phosphorus heterocyclic compounds and bis-phosphonates (5a-5g, 5f, 5g', 9 and 10) were prepared by the reaction of 4-bromo dioxaphosphepin (2) with various Grignard reagents followed by their oxidation with H2O2. All the compounds were thoroughly characterized by elemental analysis, IR, 1H, 13C, 31PNMR and mass spectral data. Their antimicrobial activity was evaluated and some of them possess significant activity.

作 者： KASTHURIAH Maddali UMA RAVI SANKAR Arigala SIVA KUMAR Bitragunta SURESH REDDY Cirandur NAGA RAJU Chamarthi   作者單位： Department of Chemistry,Sri Venkateshwara University,Tirupathi-517502,India  刊 名： 中國(guó)化學(xué)（英文版）  SCI 英文刊名： CHINESE JOURNAL OF CHEMISTRY  年，卷(期)： 2009 27(2)  分類(lèi)號(hào)： O6  關(guān)鍵詞： 1,1'-binaphthyl-2,2'-diol,4-bromo-dinaphtho[2,1-d: 1',2'-f] [1,3,2]dioxaphosphepine 4-oxide,methyle-nebis[dinaphtho-dioxaphosphepin 4-oxide],antimicrobial activity  

【Synthesis of Dinaphtho-dioxaphosphep】相關(guān)文章：

Synthesis of 4-Aminosalicylglycine04-26

Study on synthesis of polylactide from kitchen garbage04-25

Synthesis of nanosize MnO2 and its performence04-27

Synthesis and Crystal Structure of Binuclear Copper(Ⅱ)Complex Containing (Dimethylaminomethyl)ferrocene04-27

Enhanced activity of yqhD oxidoreductase in synthesis of 1,3-propanediol by error-prone PCR04-26

Synthesis and Crystal Structure of 1,4-Bis(2-hydroxymethylphenyl)-1,4-dioxabutane04-27

Synthesis and Crystal Structure of N,N-Diphenyl-3,6-diethyl-1,4-dihydro-s-tetrazine-1,4-dicarbonamide04-26

Synthesis and Crystal Structure of 1-(Trifluoromethyl)-1-(propioloyl)-(E)-3-oxo-(2-thienyl)-(2-naphthylamine)04-26

Synthesis and Structure of [Cu2(μ-NO2)(aepy)4](ClO4)3 (aepy = 2-(2-Aminoethyl)pyridine)04-27